Entry Test Preparation 2015, Chemistry BOOK 1 Chapter # 5 Chemical Bonding , MCQS with Answer Key

Entry Test Preparation 2015, Chemistry BOOK 1 Chapter # 5 Chemical Bonding , MCQS with Answer Key 

Entry Test Preparation 2015

Chemistry
Chapter # 5
CHEMICAL BONDING
You are given following questions from the topic, with four choices A through D. Select the choice that will answer the question best.
1.         Hydrogen chloride molecule contains
            A.        Covalent bond                        B.        Double bond
            C.        Co-ordinate bond                    D.        Electrovalent bond
2.         Which of the following geometry is associated with the compound in which the central atom assumes sp3d  hybrdization?
            A.        Planar                                      B.        Pyramidal
            C.        Angular                                   D.        Trigonal bipyrmidal
3.         Outermost shells of two elements X and Y have two and six electron respectively. If they combine, the expected formula of compound will be
            A.        XY                                          B.        X2Y
            C.        X2Y3                                      D.        XY2
4.         The bond angle H – O – H in ice is closet to
            A.        120o .                                      B.        60o
            C.        90o                                          D.        109o
5.         XeF4 has shape of
            A.        Sphere                                     B.        Trigonal bipyramidal
            C.        Tetrahedral                             D.        Square planar.
6.         Which of the following phenomena will occur when two atoms of the elements having same spin of electron approach for bonding?
            A.        Orbital overlap will not occur B.       Bonding will not occur
            C.        Both (A) and (B) are correct  D.        Non of the above are correct
7.         A molecule in which sp2 hybride orbitals are used by the central atom in forming covalent bonds is
            A.        He2                                         B.        SO2
            C.        PCl5                                        D.        N2
8.         Which of the following species is paramagnetic?
            A.        CO2                                         B.        O2
            C.        O2-                                          D.        CN-
9.         Which of the following hydrides has the lowest boiling point?
            A.        H2O                                        B.        H2S
            C.        H2Te                                       D.        H2S3
10.       The number of antibonding electrons in O  molecular ion on the basis of MOT is
            A.        4                                              B.        3
            C.        2                                              D.        5
11.       Antibonding MO is formed by
            A.        Addition of atomic orbitals               
B.        Substraction of atomic orbitals
            C.        Multiplication of atomic orbitala     
D.        None of these.
12.       Shape of CO2  is
            A.        Triangular pyramidal             B.        Tetrahedral
            C.        Triangular planar                    D.        Triangular bipyramidal
13.       Which of the following has zero dipole moment?
            A.        ClF                                          B.        CHCl3
            C.        SiF4                                        D.        CFCl3


14.       Which carbon is more electronegative?
            A.        sp3-hybridized carbon                       
B.        sp-hybridized carbon
            C.        sp2-hybridized carbon
            D.        always same irrespective of its hybride state

15.       In CCl4, the four valencies of carbon are directed towards the corners of a
            A.        Cube                                        B.        Hexagon
            C.        Prism                                      D.        Tetrahedron

16.       The equation for the first ionization energy of hydrogen is
            A.        H(g)   H  + e                B.        H2(g)   2H  + 2e
            C.        H2(g)   H  + e             D.        H(g) + e   H 
17.       The equation M    M+  + e represents
            A.        second ionization energy of element M
            B.        first ionization energy of elements
            C.        first ionization energy of ion M+
            D.        electron affinity of element M
18.       The shape of methonal, ammonia and water molecule can be explained by assuming
            A.        sp3 hybridization                    B.        sp2 hybridization
            C.        sp hybridization                      D.        all of these
19.       Which for the following has no dipole moment
            A.        HCl                                         B.        H2S
            C.        H2O                                        D.        CO2
20.       Which of the hydrogen halides has the highest percentage of ionic character?
            A.        HCl                                         B.        HBr
            C.        HF                                           D.        Hl
21.       Noble gases have the electronic configuration with their valance shell ns2np6 except one
            A.        He                                           B.        Ne
            C.        Kr                                            D.        Xe
22.       Two H-atom combine to form a strong H2 molecule due to
            A.        increase in potential energy   B.        decrease in potential energy
            C.        energy remains unchanged     D.        distance in increased
23.       Increase in atomic number in a period from left to right will affect the size of the atom in a way that
            A.        atomic radii decreases                        B.        atomic radii increase
            C.        no change in the atomic radii
            D.        atomic radii decrease alternatively
24.       Ca, Mg, Be, Ba, belong to the same group, the order of their ionization energy values is
            A.        Be > Mg > Ca > Ba                 B.        Ba > Ca > Mg > Be
            C.        Ca > Mg > Be > Ba                 D.        Ba > Mg > Ca > Be
25.       Which of the following is isolelectronic with krpton
            A.        Ca++                                       B.        Al+++
            C.        Br-1                                         D.        I-1
26.       Range of electronegavitity values 0 to 4. The highest electronegative atom is
            A.        oxygen                                                B.        nitrogen
            C.        carbon                                     D.        fluorine
27.       An ionic compound M2S3 is formed by the metal M, the metal is
            A.        Ca                                            B.        Ba
            C.        K                                             D.        Al
28.       Which of the following has polar bond
            A.        O2                                           B.        N2
            C.        HCl                                         D.        Cl2
29.       Which of the following molecules have multiple bonds
            A.        CH4                                         B.        C2H4
            C.        C2H6                                       D.        CCl4
30.       In H2O molecule the bond angle is
            A.        90o                                          B.        109.5o
            C.        107o                                        D.        104.5o
31.       The three N – H & bonds are made by
            A.        sp3 – s overlap                                    B.        sp2 – s overlap
            C.        P – p overlap                           D.        sp - overlap
32.       B-atom in BF3 has
            A.        sp3 hybridization                    B.        sp2 hybridization
            C.        sp hybridization                      D.        no hybridization
33.       Which of the following has two   bonds
            A.        CH4                                         B.        C2H4
            C.        C2H2                                       D.        CCl4

34.       &-bond is stronger bond than    bond because
            A.        &-bond has electron density outside the nuclei
B.        -bond has electron density along the axis between nuclei
            C.        &-bond has electron density concentrated between the nuclei
            Where   has zero electron density
D.        &-bond is made by parallel overlap of atomic orbital
35.       The theory which states that covalent bond is formed by the overlapping of two or more than two half filled atomic orbitals is
            A.        M.O. theory                            B.        V.B. theory
            C.        VSEPR theory                        D.        none of these
36.       s-character in hybrid orbital shows
            A.        sp3 hybridization                    B.        sp2 hybridization
            C.        sp-hybridization                     D.        d2sp2 hybridization
37.       Hydrogen bonding is maximum in
            A.        Ethyl chloride                         B.        Diethyl ether
            C.        Ethanol                                   D.        Non of the above
38.       Two H-atoms joined together by a covalent bond forming hydrogen molecule which have equal
            A.        electron affinity                      B.        electronegativity
            C.        both A & B                             D.        none of the above
39.       Lewis electron dot symbol of chlorine isccccc
            A.                                                       B.       
            C.                                                       D.        All of these
40.                  This Lewis dot symbol is for which of the following atoms
            A.        Sodium                                   B.        Oxygen
            C.        Nitrogen                                  D.        Flourine
41.       Which of the following sets of atoms are arranged in their order of increasing electronegativity
            A.        B < F < N                                B.        F < N < B
            C.        B < N < F                                D.        F < B < N
42.       In which of the following is the angle between the two covalent bonds greatest?
            A.        CO2                                         B.        CH4
            C.        NH3                                        D.        H2O
43.       A particular element has the following electronic configuration 1s22s22p5 , In its chemical reactions. It is most likely to
            A.        loose 1 electron                      B.        lose 7 electrons
            C.        gain 1 electron                                    D.        loose 3 electrons
44.       In diatomic molecule, in which atoms have identical electronegativities, sharing of the bonding electrons between the two atoms is      
            A.        unequal sharing                      B.        equal sharing
            C.        no sharing                               D.        none of the above
45.       Which of the following compound is covalent
            A.        H2                                           B.        KCl
            C.        MgO                                        D.        NaCl

46.       In the triple bond of acetylene, the following bonds are present
            A.        1 sigma & 2 Pi bonds             B.        2 sigma & 1 Pi bonds
            C.        3 sigma bonds                         D.        2 Pi bonds      
47.       Dipole moment of CO2 is zero. Hence the bond angle in CO2 is
            A.        109.5o                                     B.        90o
            C.        180o                                        D.        120o
48.       The bond formed in fluorine molecule is due to
            A.        s – s overlapping                    B.        s – p overlapping
            C.        p – p overlapping                    D.        p – s  overlapping
49.       Hybridization involves
            A.        bond pairs                               B.        Ione pairs
            C.        both A & B                             D.        none of these
50.       An element ‘A’ has electronic configuration 1s2 2s2 2p6 3s1 combines with element ‘B’ which has electronic configuration 1s2 2s2 2p6 3s2 3p5 . The bond between ‘A’ and ‘B’ is
A.        ionic                                        B.        covalent

            C.        co-ordinate                             D.        metall


ANSWER KEY
(CHEMICAL BONDING)

1
A
2
D
3
A
4
D
5
D
6
C
7
B
8
B
9
B
10
A
11
B
12
C
13
C
14
B
15
D
16
A
17
A
18
A
19
D
20
C
21
A
22
B
23
A
24
A
25
C
26
D
27
D
28
C
29
B
30
D
31
A
32
B
33
C
34
C
35
A
36
C
37
C
38
C
39
D
40
C
41
C
42
A
43
C
44
B
45
A
46
A
47
C
48
C
49
C
50
A




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